(2022) Chemosphere_Mechanistic investigation into flow-through electrochemical oxidation of sulfanilamide for groundwater using a graphite anode

Kim J.-G., Kim H.-B., Lee S., Kwon E.E., Baek K.

(Elsevier Ltd) Chemosphere ISSN: 456535 Vol.307 Issue. Article No.136106 DOI: 10.1016/j.chemosphere.2022.136106

The technical effectiveness/merit of electrochemical oxidation (EO) has been recognized. Nonetheless, its practical application to groundwater remediation has not been fully implemented due to several technical challenges. To overcome the technical incompleteness, this study adopted a graphite anode in the flow-through system and studied the mechanistic roles of a graphite anode. To this end, groundwater contaminated with sulfanilamide was remediated by means of EO, and sulfanilamide oxidation was quantitatively determined in this study. Approximately 60% of sulfanilamide was degraded at the anode zone, and such observation offered that the removal of sulfanilamide was not closely related with current variations (10–100 mA). However, this study delineated that sulfanilamide removal is contingent on the flow speed. For example, the removal of sulfanilamide was lowered from 59 to 25% owing to a short contact time when the flow velocity was increased from 0.14 to 0.55 cm/min. This study also delineated that a shorter anode-cathode distance could offer a favorable chance to enhance the removal of sulfanilamide even under an identical current. A shorter distance could offer a chance to save energy due to the lower voltage operation. This study also offered that chloride (Cl⁻) and sulfate (SO₄²⁻) electrolytes served a crucial role in the generation of active species. In contrast, bicarbonate (HCO³⁻) and synthetic groundwater electrolytes impeded the oxidation rate because HCO³⁻ scavenged the other active species. In an effort to seek the oxidation mechanisms of a graphite anode, scavenger, cyclic voltammetry test, and electron https://en.wikipedia.org/wiki/Electron_paramagnetic_resonanceparamagnetic resonance (EPR) analysis were done. From a series of the tests, it was inferred that a graphite anode did not directly affect the generation of the active species. Thus, the prevalence of the oxygenated functional groups on an anode surface could be the main mechanism in sulfanilamide removal due to the enhanced electron transfer. © 2022 Elsevier Ltd

Funding : This work was supported by the Korea Ministry of Environment as “The SEM (Subsurface Environment Management) projects; G232019011571 ″ and partially supported by the National Research Foundation ( NRF ), Korea, under project BK21 FOUR .