(2021) Journal of Water Process Engineering_Electrospun nanoscale iron oxide-decorated carbon fiber as an efficient heterogeneous catalyst for activating percarbonate to degrade Azorubin S in water

Hsiao C.-Y., Hung C., Kwon E., Huang C.-W., Huang C.-F., Lin K.-Y.A.

(Elsevier Ltd) Journal of Water Process Engineering ISSN: 22147144 Vol.40 Issue. Article No.101838 DOI: 10.1016/j.jwpe.2020.101838

Sodium percarbonate (2Na₂CO₃∙3H₂O₂) (PC) represents a promising alternative to H₂O₂ as PC is solid-phase, making it easier to handle; however iron (Fe) species are usually necessitated to activate PC for effectively producing hydroxyl radicals (HR) in degradation of toxicants. As homogeneous Fe species leads to severe issues of precipitation, heterogeneous iron oxide nanoparticles (NPs) seem promising but these NPs tend to aggregate in water. Thus, it is critical to develop supported iron oxide NPs. Since carbonaceous materials are one of the most useful supports, carbonaceous materials can be even fabricated into special morphologies to support iron oxide NPs. Herein, we propose to employ the electrospinning technique to develop carbon fiber (CF) as an advantageous carbon support because CF has a large aspect ratio (50:1) to allow iron oxide NPs well decorated on CF, forming a promising iron oxide NP-decorated CF (FeCF) for PC activation. FeCF is characterized using SEM, TEM, XRD, XPS, Raman spectroscopy and N₂ sorption isotherm. This FeCF can exhibit a noticeably higher catalytic reactivity than pristine Fe₂O₃ NPs for activating PC to generate HR, and then degrade a toxicant, Azorubin S (AZS). FeCF also exhibits a much lower activation energy (Ea) value of AZS degradation than other reported catalysts. Besides, FeCF could be also reusable to activate PC for degradation of AZS. Additionally, the degradation mechanism of AZS by FeCF-activated PC is also elucidated to provide insights into activation of PC and its environmental applications. These features prove that FeCF is an efficient heterogeneous catalyst to activate PC for degrading toxicants in aqueous solutions. © 2020

This work is supported by the Ministry of Science and Technology (MOST)( 109-2636-E-005-003- ), Taiwan, and financially supported by the “Innovation and Development Center of Sustainable Agriculture” from The Featured Areas Research Center Program within the framework of the Higher Education Sprout Project by the Ministry of Education (MOE), Taiwan.