(2021) Journal of Hazardous Materials_Synergistic effects of CO₂ on complete thermal degradation of plastic waste mixture through a catalytic pyrolysis platform: A case study of disposable diaper

Kwon D., Jung S., Lin K.-Y.A., Tsang Y.F., Park Y.-K., Kwon E.E.

(Elsevier B.V.) Journal of Hazardous Materials ISSN: 3043894 Vol.419 Issue. Article No.126537 DOI: 10.1016/j.jhazmat.2021.126537

Consumption of diverse plastics has posed an environmental threat because their disposal practices, landfilling and incineration, release toxic chemicals and microplastics into all environmental media. Indeed, heterogeneous matrix of plastic wastes makes them hard to be disposed. As such, this study aimed to introduce an environmentally benign/reliable disposal platform for complete decomposition of plastic wastes. Pyrolysis process was adapted to convert plastics into syngas, and a disposable diaper (DD) was used as model plastic waste, because it is composed of a variety of polymeric materials. Pyrolysis of DD resulted in the formation of gaseous products and pyrogenic oils, composed of (oxygenated) hydrocarbons. Nonetheless, reactivity of CO₂ as an oxidant in pyrolysis of DD was negligible. To impart the strong/desired reactivity of CO₂, Ni-based catalyst was adopted. Ni catalyst enhanced H₂ and CO formations 4 and 15 times more than pyrolysis without catalyst at 700 °C under CO₂. The value-added syngas production was originated from the reduction of polymeric waste, and its derivatives including aromatic compounds. Thus, CO₂ offered a strategic means to produce value-added chemicals and reduce aromaticity of pyrogenic products. The observations could offer an innovative way to control the fate of toxic chemicals derived from plastic pyrolysis. © 2021 Elsevier B.V.

This work was also supported by the National Research Foundation of Korea (NRF) grants funded by the Korea government ( MSIT ) ( NRF-2019R1A4A1027795 ). This work is financially supported by Korea Ministry of Environment (MOE) as Graduate School specialized in Climate Change.