(2020) Energy_Synergistic use of carbon dioxide in catalytic pyrolysis of chlorella vulgaris over Ni and Co catalysts

Jung S., Kim J.-H., Jeon Y.J., Park Y.-K., Kwon E.E.

(Elsevier Ltd) Energy ISSN: 3605442 Vol.211 Issue. Article No.118710 DOI: 10.1016/j.energy.2020.118710

Recovering energy from microalgal biomass via pyrolysis offers an active precautious measure for global warming due to its superior carbon fixation capability. Hence, catalytic pyrolysis of chlorella vulgaris (C. vulgaris) over Co and Ni catalysts was done to recover energy as a form of syngas. To offer a more sustainable measure for syngas formation, possible use of CO₂ as a reaction feedstock was examined. As such, functional effectiveness of CO₂ on C. vulgaris pyrolysis was mainly scrutinized. From non-catalytic pyrolysis of C. vulgaris, CO₂ turned into CO by its reduction and simultaneous oxidation of volatile pyrolysates produced from C. vulgaris pyrolysis. Such the effectiveness of CO₂ also resulted in the more gaseous pyrogenic products (syngas and C_1-2 hydrocarbons), but its effectiveness was restrictively initiated at ≥ 510 °C due to retarded reaction kinetics. To accelerate the reaction kinetics governing the formation of gaseous pyrogenic products, earth abundant and non-toxic metal Co and Ni catalysts were adopted for catalytic pyrolysis. The significant improvement of syngas production was achieved from Ni (5.6 times) and Co (2.6 times) catalysts, respectively, in reference to non-catalytic pyrolysis under the CO₂ environment. © 2020 Elsevier Ltd

This study was supported by the National Research Foundation of Korea (NRF) grants funded by the Korea government ( MSIT ) ( NRF-2019R1A4A1027795 and NRF-2019H1D3A1A01070644 ).